Friday, July 23, 2010

PERSONAL NOTES INFLUENCING MY HYPOTHESIS


CHECK OUT THIS PATENT



 THESE ARE MY PERSONAL NOTES INFLUENCING MY HYPOTHESIS



Several real-world electromagnetic problems like scattering, radiation, waveguiding etc, are not analytically calculable, for the multitude of irregular geometries designed and used. The inability to derive closed form solutions of Maxwell's equations under various constitutive relations of media, and boundary conditions, is overcome by computational numerical techniques. This makes computational electromagnetics (CEM), an important field in the design, and modeling of antenna, radar, satellite and other such communication systems, nanophotonic devices and high speed silicon electronics, medical imaging, cell-phone antenna design, among other applications.                                       Outline of Electromagnetic
















Theory, Including Problems With Step-By-Step Solutions
















            CEM problems typically solve for the problem of computing the E (Electric), and H (Magnetic) fields across the domain of the problem (i.e to calculate antenna radiation pattern, for an arbitrarily shaped antenna structure is solved by CEM). Also, power flow direction (Poynting vector), normal modes of a waveguide, dispersion of wave due to media, and scattering are quantities of interest, that can be computed from the knowledge of the E and H fields. CEM models may or may not assume symmetry, simplify real world structures to cylinders, spheres, and other regular geometrical objects. CEM models extensively make use of symmetry, and solve for reduced dimensions of the system from 3 spatial dimensions, to 2D and even 1D. CEM can be formulated into a various problems
       Wing-section optimization for supersonic viscous flow [abstract] (SuDoc NAS 1.26:199746)

depending on any of the several quantities of interest mentioned previously. An eigenvalue problem formulation of CEM allows us to calculate steady state normal modes in a structure. Transient response and impulse field effects are more accurately modeled by CEM in time domain, by FDTD. Treating curved geometrical objects is done more accurately by using finite elements FEM, or non-orthogonal grids. Beam propagation methods like BPM, solve for the power flow in waveguides. So, CEM model used is application specific, even if different techniques converge to the same field and power distributions in the modeled domain.


 Overview of methods

CEM can be used to model the domain generally by discretizing the space in terms of grids (both orthogonal, and non-orthogonal), and then solve the Maxwell's equations at each point in the grid. Naturally, such discretization of the computational space consumes computer memory, and solving the equations takes a longer time. Large scale CEM problems place computational limitations in terms of memory space, and CPU time on the computer. Generally CEM problems, as of 2007, are run on supercomputers, high performance clusters, vector processors and parallel computers; see article on, parallel computing for more computer/machine specific details. Typical formulations involve either time-stepping through the Maxwell's equations over whole domain for each time instant; or through banded matrix inversion to calculate the weights of basis functions, when modeled by finite element methods; or matrix products when using transfer matrix methods; or calculating integrals when using method of moments (MoM); or using FFT, and time iterations when calculating by the split-step method or by BPM.

Maxwell's equations in hyperbolic PDE form

Maxwell's equations can be formulated as a hyperbolic system of partial differential equations. This gives access to powerful mathematical theories for the numerical solutions of hyperbolic PDE's.



It is assumed that the waves propagate in the (x,y)-plane and restrict the direction of the magnetic field to be parallel to the z-axis and thus the electric field to be parallel to the (x,y) plane. The wave is called a transverse electric (TE) wave. In 2D and no polarization terms present, Maxwell's equations can then be formulated as





where u, A, B, and C are defined as











Integral equation solvers

 The discrete dipole approximation

The discrete dipole approximation is a flexible technique for computing scattering and absorption by targets of arbitrary geometry. The formulation is based on integral form of Maxwell equations. The DDA is an approximation of the continuum target by a finite array of polarizable points. The points acquire dipole moments in response to the local electric field. The dipoles of course interact with one another via their electric fields, so the DDA is also sometimes referred to as the coupled dipole approximation. Resulting linear system of equations is commonly solved using the conjugate gradient iterations. Because discretization matrix has symmetries (the integral form of Maxwell equations has form of convolution) it is possible to use Fast Fourier Transform to multiply matrix times vector during the conjugate gradient iterations.

 Method of moments (MOM) or boundary element method (BEM)

The method of moments (MOM) or boundary element method (BEM) is a numerical computational method of solving linear partial differential equations which have been formulated as integral equations (i.e. in boundary integral form). It can be applied in many areas of engineering and science including fluid mechanics, acoustics, electromagnetics, fracture mechanics, and plasticity.



It has become more and more popular since the 1980s. Because it requires calculating only boundary values, rather than values throughout the space defined by a partial differential equation, it is significantly more efficient in terms of computational resources for problems where there is a small surface/volume ratio. Conceptually, it works by constructing a "mesh" over the modeled surface. However, for many problems boundary element methods are significantly less efficient than volume-discretization methods (finite element method, finite difference method, finite volume method). Boundary element formulations typically give rise to fully populated matrices. This means that the storage requirements and computational time will tend to grow according to the square of the problem size. By contrast, finite element matrices are typically banded (elements are only locally connected) and the storage requirements for the system matrices typically grow quite linearly with the problem size. Compression techniques (e.g. multipole expansions or adaptive cross approximation/hierarchical matrices) can be used to ameliorate these problems, though at the cost of added complexity and with a success-rate that depends heavily on the nature of the problem being solved and the geometry involved.



BEM is applicable to problems for which Green's functions can be calculated. These usually involve fields in linear homogeneous media. This places considerable restrictions on the range and generality of problems to which boundary elements can usefully be applied. Nonlinearities can be included in the formulation, although they will generally introduce volume integrals which then require the volume to be discretized before solution can be attempted, removing one of the most often cited advantages of BEM.



 Fast multipole method (FMM)

The fast multipole method (FMM) is a computational electromagnetic technique that may be applied instead of techniques like the method of moments (MoM) or Ewald summation. It is an accurate simulation technique and is computationally more efficient than the MoM. Both memory and processor runtime requirements are greatly reduced over the MoM. The FMM was first introduced by Greengard and Rokhlin and is based on the multipole expansion technique. Can be used to accelerate MOM.



 Partial element equivalent circuit (PEEC) method

The partial element equivalent circuit (PEEC) is a 3D full-wave modeling method suitable for combined electromagnetic and circuit analysis. Unlike the method of moments (MoM), PEEC is a full spectrum method valid from dc to the maximum frequency determined by the meshing. In the PEEC method, the integral equation is interpreted as Kirchhoff's voltage law applied to a basic PEEC cell which results in a complete circuit solution for 3D geometries. The equivalent circuit formulation allows for additional SPICE type circuit elements to be easily included. Further, the models and the analysis apply to both the time and the frequency domain. The circuit equations resulting from the PEEC model are easily constructed using a modified loop analysis (MLA) or modified nodal analysis (MNA) formulation. Besides providing a dc solution, it has several other advantages over a MoM analysis for this class of problems since any type of circuit element can be included in a straightforward way with appropriate matrix stamps. The PEEC method has recently been extended to include nonorthogonal geometries.[1] This model extension, which is consistent with the classical orthogonal formulation, includes the Manhattan representation of the geometries in addition to the more general quadrilateral and hexahedral elements. This helps in keeping the number of unknowns at a minimum and thus reduces computational time for nonorthogonal geometries.
Finite-difference time-domain (FDTD) is a popular computational electrodynamics modeling technique. It is considered easy to understand and easy to implement in software. Since it is a time-domain method, solutions can cover a wide frequency range with a single simulation run.



The FDTD method belongs in the general class of grid-based differential time-domain numerical modeling methods. Maxwell's equations (in partial differential form) are modified to central-difference equations, discretized, and implemented in software. The equations are solved in a leapfrog manner: the electric field is solved at a given instant in time, then the magnetic field is solved at the next instant in time, and the process is repeated over and over again.



The basic FDTD algorithm traces back to a seminal 1966 paper by Kane Yee in IEEE Transactions on Antennas and Propagation. The descriptor "Finite-difference time-domain" and its corresponding "FDTD" acronym were originated by Allen Taflove in a 1980 paper in IEEE Transactions on Electromagnetic Compatibility. Since about 1990, FDTD techniques have emerged as primary means to model many scientific and engineering problems dealing with electromagnetic wave interactions with material structures. Current FDTD modeling applications range from near-DC (ultralow-frequency geophysics involving the entire Earth-ionosphere waveguide) through microwaves (radar signature technology, antennas, wireless communications devices, digital interconnects, biomedical imaging/treatment) to visible light (photonic crystals, nanoplasmonics, solitons, and biophotonics). Approximately 30 commercial and university-developed FDTD software suites are available for use (see below).

MATHMATICIANS

Wave propagation and underwater acoustics (Lecture notes in physics)

Joseph B. Keller (born July 31, 1923, Paterson, New Jersey) is an American mathematician who specializes in applied mathematics. He is best known for his work on the "Geometrical Theory of Diffraction" (GTD). [1]




He obtained his PhD in 1948 from New York University under the supervision of Richard Courant. He was a Professor of Mathematics in the Courant Institute at New York University until 1979. Then he was Professor of Mathematics and Mechanical Engineering at Stanford University until 1993, when he became Professor Emeritus.








He has a brother who was also a mathematician, Herbert B. Keller, at Caltech who has studied numerical analysis, scientific computing, bifurcation theory, path following and homotopy methods, computational fluid dynamics. Both have contributed to the fields of electromagnetics and fluid dynamics.

Numerical Methods for Two-Point Boundary Value Problems.Interview with Herbert B. Keller

      (California Institute of Technology Oral History Project)

He worked on the application of mathematics to problems in science and engineering, such as wave propagation. He contributed to the Einstein-Brillouin-Keller method for computing eigenvalues in quantum mechanical systems.














In 1988 he was awarded the U.S. National Medal of Science, and in 1997 he was awarded the Wolf Prize, by the Israel-based Wolf Foundation. In 1996, he was awarded the Nemmers Prize in Mathematics.

OPTIC NTS

















^ Longhurst RS, Geometrical and Physical Optics, 2nd Edition, 1968, Longmans [London]


Sunday, July 11, 2010

Steps toward Global Mind Control

Steps toward Global Mind Control

radio frequency heating

MagicMojo87@gmail.com

My Account
Sign out Advanced Patent Search

High capacity ion cyclotron resonance cell Michael SenkoOverview

Abstract

› Drawing

Description

Claims





Patent number: 6573495

Filing date: Dec 26, 2000

Issue date: Jun 3, 2003

Application number: 9/750,503







Page images PDF

US006573495B2



(12) United States Patent



Senko



(io) Patent No.: US 6,573,495 B2 (45) Date of Patent: Jun. 3,2003



(54) HIGH CAPACITY ION CYCLOTRON RESONANCE CELL



(75) Inventor: Michael Senko, Sunnyvale, CA (US)



(73) Assignee: Thermo Finnigan LLC, San Jose, CA (US)



( * ) Notice: Subject to any disclaimer, the term ol this patent is extended or adjusted under 35 U.S.C. 154(b) by 317 days.



(21) Appl. No.: 09/750,503



(22) Filed: Dec. 26, 2000



(65) Prior Publication Data



US 2002/0079444 Al Jun. 27, 2002



(51) Int. Cl.7 ................................................. H01J 49/38



(52) U.S. Cl ........................ 250/290; 250/291; 250/292;



250/423 R (58) Field of Search ................................. 250/290, 291,



250/292, 293, 423 R



(56) References Cited



U.S. PATENT DOCUMENTS



Caravatti et al., "The 'Infinity Cell': A New Trapped-ion Cell With Radio frequency Covered Trapping Electrodes For Fourier Tansform Ion Cyclotron Resonance Mass Spectrom- etry," John Wiley & Sons, Ltd., 1991, pp. 514-518. Chen et al., "An Off-Center Cubic Ion Trap For Fourier Transform Ion Cyclotron Resonance Mass Spectrometry," MASPEC Compuscript, Jan. 1994, pp. 1-10. Guan et al., "Off-axis Injection Into An ICR Ion Trap: A Means For Efficient Capture Of A Continuous Beam Of Externally Generated Ions," Elsevier Science B.V., 1994, pp. 75-86. Lee et al., "A New Cylindrical Trapped Ion ICR Cell", Institute of Physical and Theoretical Chemistry, University of Frankfurt, Germany, pp. 1645-1649. Marto et al., "A Two-Electrode Ion Trap For Fourier Trans- form Ion Cyclotron Resonance Mass Spectrometry," Elsevier Science B.V., 1994, pp. 9-30. Rempel et al, "Parametric Mode Operation Of A Hyperbolic Penning Trap For Fourier Transform Mass Spectrometry," American Chemical Society, 1987, pp. 2527-2532. Winger et al., "High Throughput, High Speed, Automated Accurate Mass LC-FT/MS Analysis," Finnigan Corpora- tion, p. 516. * cited by examiner



Primary Examiner—John R. Lee



Assistant Examiner—Nikita Wells



(74) Attorney, Agent, or Firm—Dorsey & Whitney LLP



Ion Injection R



VDC



Magnetic Field



VDC



Excitation Voltage



Detection Signal







US 6,573,495 B2



HIGH CAPACITY ION CYCLOTRON RESONANCE CELL



BRIEF DESCRIPTION OF THE INVENTION



This invention relates generally to an ion cyclotron resonance (ICR) cell, and more particularly to an ICR cell with large ion storage capacity.



BACKGROUND OF THE INVENTION



Ion cyclotron resonance is well known and has been employed in numerous spectroscopy devices and studies. Generally, these devices store the ions to be analyzed in cells of various configurations which are disposed in a uniform magnetic field. Gaseous ions in the presence of the uniform magnetic field are constrained to move in circular orbits in a plane perpendicular to the field (cyclotron oscillations). The ions are not constrained in their motion parallel to the field. As a consequence, various cell configurations have been adopted to retain the ions within the cell. For example, the cell may include end plates which have dc voltages applied thereto, or it may be of an open cell design such as described by Beu et. al., "Open trapped ion cell geometries for FT/ICR/MS, Int. J. Mass Spectrom. Ion Processes, 112 (1992), 215-230. Another cell configuration is described in U.S. Pat. No. 5,019,706.



The frequency of the circular motion is directly dependent upon the charge-to-mass ratio of the ions and the strength of the magnetic field. When orbiting ions trapped within the cell are subjected to an oscillating electric field, disposed at right angles to the magnetic field, the ions having a cyclotron frequency equal to the frequency of the oscillating electric field are accelerated to increasingly larger orbital radii and higher kinetic energy. Because only the resonant ions absorb energy from the oscillating field, they are distinguished from the non-resonant ions upon which the oscillating electric field has a substantially negligible effect. The oscillating ions are detected by separate electrodes which have image current induced therein by the oscillating ions. In another example, the cell does not include separate detection electrodes, and is operated in a switched mode. A twoelectrode ion trap is described by Marto, et al., "A TwoElectrode Ion Trap for Fourier Transform Ion Cyclotron Resonance Mass Spectrometry", Int. J. Mass Spectrom. Ion Processes, 137 (1994), 9-30.



Generally, the ions are excited by a pulsed wave form having multiple frequencies whereby ions of different masses undergo ion cyclotron resonance. Comisarow and Marshall in U.S. Pat. No. 3,937,955 describes the operation of an ICR cell excited with waveforms having multiple frequencies in what is known as a Fourier transform mode (FT-ICR). It has been recently demonstrated that one of the primary limitations to obtaining accurate mass measurement for FT-ICR is space charge-induced shifts of the cyclotron frequency. These shifts can be minimized by having a reproducible number of ions during each scan (Winger, et al., "High Throughput, High Speed, Automated Accurate Mass LC-FT/MS Analysis", Proc. 46th ASMS (1998), p. 516).



Other FT-ICR systems are less sensitive to space chargeinduced shifts and therefore produce more reliable mass accuracy data. For example, the infinity cell (Caravatti et al., "The Infinity Cell: a new Trapped-ion Cell With Radiofrequency Covered Trapping Electrodes for Fourier Transform Ion Cyclotron Resonance Mass Spectrometry", Org. Mass Spectrom., 26 (1991), 514-518) (Allemann et al., "Ion



Cyclotron Resonance Spectrometer", U.S. Pat. No. 5,019, 706), which uses a linearized dipolar field which allows a greater ion excitation radius and the use of "side-kick" injection (Caravatti, Pablo, "Method and apparatus for the



5 accumulation of ions in a trap of an ion cyclotron resonance spectrometer, by transferring the kinetic energy of the motion parallel to the magnetic field into direction perpendicular to the magnetic field", U.S. Pat. No. 4,924,089), which gives the ions an initial non-zero magnetron radius.



10 Both of these features contribute to lower ion density and thus a reduced sensitivity to space charge-induced frequency shifts.



The primary drawback to a non-zero initial magnetron radius is that the acquired signal will contain significant



15 harmonic content and other modulations of the fundamental signal (Chen et al., "An off-center cubic ion trap for Fourier transform ion cyclotron resonance mass Spectrometry", Int. J. Mass Spectrom. Ion Processes, 133 (1994), 29-38). One method which allows the formation of an off-axis ion cloud



20 without the observation of higher-order harmonics is the use of a two-electrode trap such as described by Marto et. al., "A Two-Electrode Ion Trap for Fourier Transform Ion Cyclotron Resonance Mass Spectrometry", Int. J. Mass Spectrom. Ion Processes, 137 (1994), 9-30. This trap has been shown



25 to be an order of magnitude less sensitive to space charge shifts than a standard cubic trap. The primary disadvantage of the two-electrode trap is the severe axial ejection caused by the parametric excitation and significant axial fields.



OBJECTS AND SUMMARY OF THE 30 INVENTION



It is an object of the present invention to provide an improved ICR cell.



It is a further object of the present invention to provide an 35 ICR cell in which the ion cloud is off-axis.



It is a further object of the present invention to provide an ICR cell in which space charge-induced shifts are minimized.



The foregoing and other objects of the invention are



40 achieved by an ICR cell which comprises two concentric



elongated electrodes and trapping electrodes disposed at the



ends of the concentric electrodes to form an ion trapping



volume in the space between the concentric electrodes.



BRIEF DESCRIPTION OF THE DRAWINGS



45



The foregoing and other objects of the invention will be



more clearly understood from the following description when read in conjunction with the accompanying drawings in which:



50 FIG. 1 is a sectional view of an ICR cell with two concentric cylindrical electrodes and end trapping electrodes disposed perpendicular to the magnetic field.



FIG. 2 is a sectional view taken along the line 2—2 of FIG. 1. 55 FIG. 3 is a perspective view of the cell of FIGS. 1 and 2.



FIG. 4 is a sectional view of an ICR cell with concentric cylindrical electrodes and end trapping electrodes disposed parallel to the magnetic field.



FIG. 5 is an end view of an ICR cell with spaced square 60 concentric electrodes.



FIG. 6 is an end view of an ICR cell with spaced hexagonal concentric electrodes.



DESCRIPTION OF PREFERRED 65 EMBODIMENTS



Referring to FIGS. 1, 2 and 3, an ICR cell in accordance with one embodiment of the invention is illustrated. The cell



« PreviousContinue »


MagicMojo87@gmail.com

My Account
Sign out Advanced Patent Search

High capacity ion cyclotron resonance cell Michael SenkoOverview

Abstract

Drawing

Description

Claims





Patent number: 6573495

Filing date: Dec 26, 2000

Issue date: Jun 3, 2003

Application number: 9/750,503







Page images PDF

US 6,573,495 B2



25



includes spaced hollow cylindrical electrodes 11 and 12 which define an annular trapping space 13. Although shown as a hollow electrode, the electrode 11 need not be a hollow electrode.



Trapping electrodes 16 and 17 perpendicular to the mag- 5 netic field are spaced from the ends of the cylindrical electrodes and, as is well known, serve to confine ions within the trapping region 13. Ions are introduced into the region 13 by injecting off-axis from a suitable external source as indicated by the arrow 18. The off-axis injection provides a :o component of ion travel which is perpendicular to the magnetic field, and gives rise to magnetron motion as indicated by the curve 19, FIG. 2, in which the ions orbit around the central cylinder. This orbiting reduces the axial velocity of the ions and provides a greater dwell time within :5 the ion trap. The ion trap is shown disposed in a uniform magnetic field and is enclosed within an evacuated chamber or envelope (not shown). Alternatively, the ions can be formed by bombarding molecules within the trapping volume with an ion beam, that is the ions are formed in the 20 trapping volume.



In operation, a dc voltage (VDC) is applied to the trapping electrodes. The two-electrode cyclotron resonance cell is operated by applying a broad-frequency band excitation pulse between the electrodes to form radially-extending electric fields which cause the ions to absorb energy and oscillate in the radial direction. After the excitation pulse is applied, the electronic switch 23 is switched to the detect mode where image currents induced by the cyclotron motion of the ions are detected. The image currents are processed as for example by the Fourier Transform method taught in U.S. Pat. No. 3,937,955. The action of the off-axis injection produces an actual magnetron motion of the ions and causes them to orbit about the inner electrode which significantly reduces the ion densities relative to a traditional ion trap.



FIG. 4 shows an ICR cell in which the hollow trapping electrodes 26 and 27 are concentric electrodes disposed parallel to the magnetic field. This type of open-cell design is described in Beu et al. article entitled: "Open trapped ion 4Q cell geometries for FT/ICR/MS", Int. J. Mass Spectrom. Ion Processes, 112 (1992) 215-230. In all other respects, the cell is operated as described above.



FIG. 5 is a sectional view showing an ion cyclotron resonance cell in which the concentric electrodes lla, 12a 45 are rectangular tubes. Trapping electrodes are disposed at the ends of the tubes. The ICR cell operates substantially as described above. FIG. 6 shows an ion cyclotron resonance cell which has tubular electrodes of a hexagonal shape. It is understood, however, that, although circular cylindrical cells 59 are preferred, electrodes comprising concentric square tubes, hexagonal tubes or other configurations will work as described above. Thus, there has been disclosed an ICR cell with an increased storage space thereby minimizing space charge effects. 55



The foregoing descriptions of specific embodiments of the present invention are presented for the purposes of illustra



tion and description. They are not intended to be exhaustive or to limit the invention to the precise forms disclosed; obviously many modifications and variations are possible in view of the above teachings. The embodiments were chosen and described in order to best explain the principles of the invention and its practical applications, to thereby enable others skilled in the art to best utilize the invention and various embodiments with various modifications as are suited to the particular use contemplated. It is intended that the scope of the invention be defined by the following claims and their equivalents.



What is claimed is:



1. An ion cyclotron resonance cell comprising first and second elongated spaced concentric electrodes having a common axis to define in the space therebetween an ion trapping volume formed by the by the concentric electrodes; and trapping electrodes disposed at the ends of said elongated first and second electrodes.



2. An ion cyclotron resonance cell as in claim 1 including trapping electrodes disposed at the ends of said elongated electrodes.



3. An ion cyclotron resonance cell as in claim 1 in which the elongated spaced electrodes are parallel to one another.



4. An ion cyclotron resonance cell as in claims 2 or 3 in which the elongated electrodes are cylindrical tubes.



5. An ion cyclotron resonance cell as in claim 2 or 3 in which the elongated electrodes are square tubes.



6. An ion cyclotron resonance cell as in claim 2 or 3 in which the elongated electrodes are multi-sided tubes.



7. An ion cyclotron resonance cell as in claim 2 in which the trapping electrodes are disposed perpendicular to the axis of the cell.



8. An ion cyclotron resonance cell as in claim 2 in which the trapping electrodes are disposed parallel to the axis of the cell.



9. An ion cyclotron resonance cell comprising



a first elongated hollow outer electrode,



a smaller second elongated electrode within the first electrode to define a concentric ion trapping volume in the space therebetween,



mapping electrodes disposed at the ends of the elongated first and second electrodes,



switch means for selectively applying electrical excitation pulses between the elongated electrodes for exciting ions within said trapping volume and for detecting image currents induced by ions in said trapping volume responsive to motion created by said excitation pulses.



10. An ion cyclotron resonance cell as in claim 9 in which the elongated electrodes are concentric.



11. An ion cyclotron resonance as in claim 10 in which the elongated electrodes are cylindrical.



12. An ion cyclotron resonance cell as in claim 10 in which the elongated electrodes are multi-sided.


http://www.google.com/patents?pg=PA2&id=FMUiAAAAEBAJ&output=text



Method and apparatus for the accumulation of ions in a trap of an ion ...
http://www.google.com/patents/about?id=1AR8AAAAEBAJ&output=text


http://www.google.com/patents/about?id=VO4HAAAAEBAJ&dq=Dielectric+Heating
Capacative dielectric heating system
 
http://www.google.com/patents/about?id=I7gRAAAAEBAJ&dq=ion+cyclotron
 
Apparatus and method for ion cyclotron resonance mass spectrometry
 
Patent Number Title Issue date


3937955 Fourier transform ion cyclotron resonance spectroscopy method and apparatus Feb 10, 1976

4682027 Method and apparatus for sample confirmation in gas chromatography Jul 21, 1987

4959543 Method and apparatus for acceleration and detection of ions in an ion cyclotron resonance cell Sep 25, 1990

ION CYCLOTRON RESONANCE MASS SPECTROMETER WITH MEANS FOR IRRADIATING
 
http://www.google.com/patents/about?id=jEpkAAAAEBAJ&output=text
 
http://www.google.com/patents/about?id=5nciAAAAEBAJ
 
http://www.google.com/patents?id=d3s7AAAAEBAJ&pg=PA3&source=gbs_selected_pages&cad=3#v=onepage&q&f=false
 
http://www.google.com/patents/about?id=1AR8AAAAEBAJ&output=text
 
Patent Number Title Issue date


4924089 Method and apparatus for the accumulation of ions in a trap of an ion cyclotron resonance spectrometer, by transferring the kinetic energy of the motion parallel to the magnetic field into directions perpendicular to the magnetic field May 8, 1990

4931640 Mass spectrometer with reduced static electric field Jun 5, 1990

5019706 Ion cyclotron resonance spectrometer May 28, 1991

5389784 Ion cyclotron resonance cell Feb 14, 1995

5650617 Method for trapping ions into ion traps and ion trap mass spectrometer system thereof
http://www.google.com/patents?tbs=bks%3A1&tbo=1&q=radio+frequency+heating+&btnG=Search+Patents

radio frequency heating

http://www.google.com/patents/about?id=SZBFAAAAEBAJ&dq=radio+frequency+heating





 
 
 
 

what r those poles out there

Multi-ion, multi-event test of ion cyclotron resonance heating a semiannual status report, September 1, 1993 - December 30, 1993 (SuDoc NAS 1.26:194859)Ion Cyclotron Resonance Spectrometry


Ion Cyclotron Resonance Spectrometry (Lecture Notes in Chemistry, 7)






[54] METHOD AND APPARATUS FOR THE



ACCUMULATION OF IONS IN A TRAP OF AN ION CYCLOTRON RESONANCE SPECTROMETER, BY TRANSFERRING THE KINETIC ENERGY OF THE MOTION PARALLEL TO THE MAGNETIC FIELD INTO DIRECTIONS PERPENDICULAR TO THE MAGNETIC FIELD [75] Inventor:



Pablo Caravatti, Winterthur, Switzerland



[73] Assignee: Spectrospin AG, Switzerland



[21] Appl. No.: 251,192



[22] Filed: Sep. 29,1988



[30] Foreign Application Priority Data

Fast Wave Resonance Near the Ion Cyclotron Frequency A Dissertation in Electrical Engineering Submitted to the Graduate Faculty of Texas Tech University in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy

Oct. 7, 1987 [DE] Fed. Rep. of Germany 3733853



[51] Int. CI.5 H01J 49/36



[52] U.S. Q 250/290; 250/291



[58] Field of Search 250/290, 291, 293, 281,



250/282, 288

Ion Cyclotron Resonance Spectrometry II (Lecture Notes in Chemistry)


A semiannual status report on the study of the multi-ion, multi-event test of ion cyclotron resonance heating, reporting period, May 8, 1993 - August 30, 1993 (SuDoc NAS 1.26:194134)


U.S. PATENT DOCUMENTS



3,502,867 3/1970 Beauchamp 250/290
Ion cyclotron resonance spectrometry II


3,922,543 11/1975 Beauchamp 250/290

The effect of finite ion and electron temperatures on the ion cyclotron resonance instability (A.E.R.E. reports;no.CLM;R32)

3,984,681 10/1976 Fletcher et al 250/290

Multi-species test of ion cyclotron resonance heating at high altitudes (SuDoc NAS 1.26:206145)

4,563,579 1/1986 Kellerhals et al 250/291

Electron Cyclotron Resonance Ion Sources: The Basis, Developments and the State of the Art

4,581,533 4/1986 Littlejohn et al 250/282

Electron Cyclotron Resonance Ion Sources and ECR Plasmas

4,686,365 8/1987 Meek et al 250/281



4,739,165 4/1988 Ghaderi et al 250/290



4,746,802 5/1988 Kellerhals 250/291



4,761,545 8/1988 Marshall et al 250/291



4,818,864 4/1989 Alleman 250/291


Ion cyclotron wave growth calculated from satellite observations of the proton ring current during storm recovery: By J.A. Joselyn and L.R. Lyons, Space ... Research Laboratories (SEL preprint)


Method and apparatus for introducing ions into an ion trap of an ion cyclotron resonance spectrometer, the ion trap being arranged in a constant homogeneous magnetic field and comprising walls which are designed as electrodes and extend in parallel and/or perpendicularly to a symmetry axis having the direction of the magnetic field and which are supplied with electric trapping potentials retaining the ions in the ion trap, one of the walls which extend perpendicularly to the magnetic field being provided with a hole, the method including the steps of generating the ions outside the ion trap, forming the ions into an ion beam, directing the ion beam upon the hole in the one wall of the ion trap, in the direction of the magnetic field, and reducing thereafter the velocity component, in the direction of the magnetic field, of the ions which have passed the hole and entered the ion trap, below the value determined by the trapping potentials which is needed by the ions for leaving the ion trap, characterized in that the ions that have entered the ion trap are imparted a second motion component in a direction perpendicular to the magnetic field, such that the magnitude of the vector sum of the two ion velocity components remains the same.



11 Claims, 1 Drawing Sheet



130



109





METHOD AND APPARATUS FOR THE ACCUMULATION OF IONS IN A TRAP OF AN



ION CYCLOTRON RESONANCE



SPECTROMETER, BY TRANSFERRING THE 5



KINETIC ENERGY OF THE MOTION PARALLEL



TO THE MAGNETIC FIELD INTO DIRECTIONS



PERPENDICULAR TO THE MAGNETIC FIELD



The present invention relates to a method for intro- 10 ducing ions into the ion trap of an ion cyclotron resonance spectrometer, the ion trap being arranged in a constant homogenous magnetic field and comprising walls which are designed as electrodes and extend in parallel and/or perpendicularly to the direction of the 15 magnetic field and which are supplied with electric trapping potentials retaining the ions in the ion trap, one of the walls which extends perpendicularly to the magnetic field being provided with a hole, the method including the steps of generating the ions outside the ion 20 trap, forming the ions into an ion beam, directing the ion beam upon the hole in the one wall of the ion trap, in the direction of the magnetic field, and reducing thereafter the velocity at which the ions which have passed the hole and entered the ion trap move in the direction of 25 the magnetic field, below the value determined by the trapping potentials which is needed by the ions for leaving the ion trap.



A method of this kind has been known before from DE-OS 35 15 766. The known method has two variants. 30 One of these variants consists in increasing temporarily the gas pressure in the ion trap for reducing the velocity of the ions that have entered the ion trap, in order to slow down the ions. This variant requires that gas has to be pumped off after the ions have been shot in, which 35 not only extends the process time but may lead also to ion losses and fragmentation of the ions.



According to other variants, the velocity of the ions is reduced by a decelerating electrode arranged upstream of the ion trap, and at the same time the trapping 40 potentials are switched off to enable the ions to enter the ion trap in spite of their reduced velocity. Thereafter, the trapping potentials are switched on again so as to trap the ions present in the ion trap. However, this variant is also not capable of achieving in the ion trap 45 the ion concentration maximally possible and desirable to obtain the best possible sensitivity for recording the ion cyclotron resonance spectrum.



Now, it is the object of the present invention to provide a method for slowing down the speed, in the direc- 50 tion of the magnetic field, of those ions which have entered the ion trap, which method be carried out easily and results in increased density of the trapped ions.



This object is achieved according to the invention by the fact that the ions that have entered the ion trap are 55 imparted a motion component in a direction perpendicular to the magnetic field.



Consequently, the velocity of the ions in the direction of the magnetic field, which enables the ions to leave the ion trap, is slowed down in the case of the method 60 according to the invention not by increasing the gas pressure, or by providing a decelerating electrode, but rather by causing the ions to drift off their original path of movement in the direction of the magnetic field so that once the ions have entered the ion trap they will 65 move along a path which results in an extension of their average dwelling time in the ion trap. This increases considerably the period of time during which the ions



are permitted to accumulate, and the ion flow can be maintained until the maximum ion density, which is limited by the average dwelling time, has been reached in the ion trap. It is a particular advantage in this connection that no critical operating parameters have to be adhered to, as regards the value or the duration of the potentials to be applied.



According to a particularly simple embodiment of the method according to the invention, the ions are introduced into the ion trap along an axis set off laterally from the axis of symmetry of the ion trap extending in parallel to the magnetic field. This can be achieved simply by arranging the ion beam and the ion trap with a certain lateral offset relative to each other. Due to this lateral offset, the ions entering the ion trap get into an area where the electric field prevailing due to the potentials applied to the walls of the ion trap exhibits a transversal component which leads to a certain lateral deflection of the ions. The ions are thereby forced to perform a cyclotron movement along paths which result hi the desired extension of the dwelling time of the ions in the ion trap.
A Brief History of the Harvard University Cyclotrons (Department of Physics)


Cyclotrons and Their Applications: Proceedings of the 14th International Conference, Cape Town, South Africa 8 - 13 October 1995


The cyclotron (Methuen's Monographs on physical subjects series)





According to another variant of the method according to the invention, an electric field directed transversely to the direction of the magnetic field is generated during the time of application of the ion beam, and preferably in the direct neighborhood of that wall of the ion trap which is provided with the hole. Such a field may be generated in a simple manner by means of additional electrodes arranged in the ion trap. Neither the value nor the duration of application of the field are critical. However, the field has to be switched off before the spectra-recording process proper is commenced.















It may be convenient for both variants of the method to reduce the potential of that wall of the ion trap, which is provided with the hole, below the trapping potential during application of the ion beam, so that the ions can be shot into the ion trap at reduced axial velocity, which has a favorable influence on the trapping process.

Axial velocity measurements in reacting and non-reacting flow in a centerbody combustor


The effect of change in axial velocity on the potential flow in cascades (Aeronautical Research Council. Reports & memoranda, no.3547)



Axial velocity streaks in the jet stream: Ageostrophic "inertial" oscillations (Technical report)




Particle Impact on the Wall of Gas/Solids Transfer Lines: A Non-Intrusive Probe of Axial Flow Velocity


The effect of change in axial velocity on the potential flow in cascades, (Aeronautical Research Council. Reports and memoranda, no. 3547)




Analysis of geometry and design-point performance of axial-flow turbines using specified meridional velocity gradients (NASA contractor report)



The present invention further relates to an ion cyclotron resonance spectrometer adapted for carrying out the method according to the invention. It comprises in the conventional manner an ion trap which is arranged in a constant homogeneous magnetic field and comprises walls which are designed as electrodes and extend in parallel or perpendicularly to the direction of the magnetic field and which are supplied with electric trapping potentials retaining the ions in the ion trap, one of the walls extending perpendicularly to the magnetic field being provided with a hole. The spectrometer further comprises means for introducing ions into the ion trap comprising an ion source, means for generating an ion beam which is emitted by the ion source in the direction of the magnetic field and directed upon the hole in the one wall of the ion trap, and means for reducing the velocity at which the ions which have passed the hole and entered the ion trap move in the direction of the magnetic field, below the value determined by the trapping potentials which is needed by the ions for leaving the ion trap.



According to the invention, the means for reducing the velocity of the ions in the direction of the magnetic field are adapted for imparting to the ions that have entered the ion trap a motion component perpendicular to the direction of the magnetic field.



4,924,089



According to one embodiment of the spectrometer according to the invention, the hole arranged in one wall of the ion trap is laterally offset relative to that axis of symmetry of the ion trap which extends parallel to the magnetic field. 5



According to another embodiment of such a spectrometer, electrodes which are insulated from the wall and which are connected to a voltage source that can be switched on in pulse-like manner are arranged on both sides of the hole provided in the one wall of the ion trap. 10 It will be appreciated that such electrodes can be used also when the hole provided in the one wall of the ion trap is set off from the center of the wall.



Further, the potential of the wall opposite the wall provided with the hole may differ from the potential of 15 the wall provided with the hole, with respect to the ionic charge.



It will be appreciated that the method according to the invention does not require any complicated measures regarding the design of the spectrometer, but can 20 be effected with relatively small modifications which do not oppose the application of the method according to the invention.



The invention will now be described and explained in more detail with reference to the embodiments illus- 25 trated in the drawing. The features that can be derived from the description and the drawing may be used in other embodiments of the invention either individually or in any desired combination. In the drawing:



FIG. 1 shows a diagrammatic representation of a first 30 embodiment of an ion cyclotron resonance spectrometer according to the invention;



FIG. 2 shows a diagrammatic representation of a second embodiment of an ion cyclotron resonance spectrometer according to the invention; and 35



FIG. 3 shows a time diagram illustrating the different process steps to be carried out when operating the ion cyclotron resonance spectrometer according to FIG. 2.



The ion cyclotron resonance spectrometer illustrated diagrammatically in FIG. 1 comprises an ion source 1 in 40 the form of a cell coacting with an electron gun 2 by which an electron beam 3 indicated by a broken line can be shot into the chamber 1 for ionizing the gas contained in the said cell. A wall 4 of the ion source 1 is provided with a small hole 5 through which the ions 45 can leave the ion source 1. The ion source 1 is followed by a flight channel 6 which extends coaxially to the hole 5 in the wall 4 of the ion source 1 and which, when the system is operated with positive ions, is maintained in operation at a relatively high potential of — 1 kV to — 3 50 kV. The end of the flight channel 6 opposite the ion source 1 is equipped with a mask 7 provided with a hole 8 through which the ion beam 9 formed by means of the flight channel 6 and indicated in the figure by a broken line is permitted to escape from the flight channel 6. 55 The flight channel 6 is followed by an ion trap 10 comprising two walls 11, 12 extending perpendicularly to the direction of the ion beam 9, and four walls extending in parallel to this direction. Of the last-mentioned four walls, only the two walls 13, 14 extending perpendicu- 60 larly to the drawing plane can be seen, while the other two walls extend in parallel to the drawing plane. The wall 11 of the ion trap neighboring the flight channel 6 is provided with a hole 15 upon which the ion beam 9 is directed. The ion beam 9 extends in parallel to the axis 65 16 of the ion trap, but is laterally offset relative to this axis. Between the end of the flight channel 6 and the ion trap 10 a decelerating electrode 17 is arranged for slow



ing down the ions to a suitable potential before they enter the ion trap. Typical operating potentials for the walls of the ion trap are 0 V for the wall 11 neighboring the flight channel 6, +0.5 V for the wall 12 extending in parallel thereto, 1 V for the walls which extend in parallel to the ion beam and of which only the walls 13, 14 are shown, and —0.5 V for the decelerating electrode. It is noted here once more that all these values apply to the examination of positive ions. If negative ions are to be examined, potentials with inverse signs are employed. In operation, the ion trap is located in a constant homogeneous magnetic field B extending in parallel to the direction of the ion beam 9 and to the axis 16 of the ion beam 10. The magnetic field is indicated in the drawing by arrows.



Although in operation of the ion cyclotron resonance spectrometer illustrated in FIG. 1 the impulse of the ions introduced into the ion trap 10 in the form of the ion beam 9 is largely reduced, it must still be sufficiently great to enable the ions to overcome the potential of the wall 11 of the ion trap adjacent the flight channel 6. This impulse is generally sufficient also to enable the ions to reach the other wall 12 extending perpendicularly to the direction of the ion beam and to the magnetic field B, and to get lost—either by impinging upon this wall or by escaping from the ion trap through a hole 18 arranged in the wall 12 concentrically to the axis 16 of the ion trap 10—in case the ion beam would enter the ion trap along the axis 16. However, in the case of the embodiment illustrated in FIG. 1, the ion beam 9 is offset relative to the axis 16 of the ion trap 10 so that it enters an area of the ion trap 10 where the electrostatic field existing inside the ion trap 10 and obtained inside the ion trap as a result of the potentials applied to the walls, comprises certain component directed transversely to the axis 18 with the result that when the ions enter the ion trap 10 they are deflected from their straight path, due to the prevailing magnetic field and the electrostatic field, whereby their impulse component in the direction of the cell axis 16 is reduced below the value needed to cause the ions to leave the cell immediately. It is ensured in this manner that the dwelling time of the ions that have entered the ion trap 10 is increased quite considerably and that, accordingly, a very high ion density can be obtained by accumulation of the ions during their dwelling time. The duration of the ion beam required for achieving a high ion density in the ion trap corresponds to the maximally achievable dwelling time of the ions; it is in the range of between 10 and 500 ms and determined, amount other things, by the intensity of the ion flow.



The embodiment of an ion cyclotron resonance spectrometer illustrated in FIG. 2 comprises again an ion source 101 in the form of a cell filled with gas into which an ionizing beam 103 an be shot by means of an electron gun 102 or a laser. The ions leaving the ion source 101 are again formed into an ion beam 109, by means of a flight channel 106, and the ion beam 109 is permitted to leave the flight channel through the hole 108 in a mask 107 provided at the end of the flight channel opposite the ion source 101. The ion beam 109 is directed upon an ion trap 110 which, just as in the case of the embodiment of FIG. 1, comprises walls 111 and 112 extending perpendicularly to the ion beam 109 and walls 113 and 114 extending in parallel to the beam. The wall 111 facing the flight channel 106 is again provided with an opening 115, but here the opening 115 is arranged concentrically to the axis 116 of the ion trap.